MATERIALS AND METHODS OF DETERMINING PHYSICAL PROPERTIES OF THE SELECTED RICE

Source of Raw Material
            The selected rice variety  IWA I, IWA 2, IWA 3, IWA 6, IWA 7, IWA 8, FARO 44, FARO 52, Agreement and Argwula rice varieties shall be collected from the Biotechnology Research centre Ebonyi State University Abakaliki.
3.2       Sample Preparation
            The samples shall be cleaned manually to remove lighter foreign matter such as dust, dirt, chaff, immature and broken kernels.

3.3       Moisture Determination  
           The initial moisture content of the kernels shall be determined using hot air oven method (Tabatabaeefar, 2003). 100 kernels of the rice shall be weighed using a sensitive electronic balance to an accuracy of 0.00g and shall be recorded. The weight of an empty washed and dried petri dish shall be weighed and recorded as W1. The sample and the petri dish shall be weighed together and recorded as W2. The sample and the petri dish shall be dried in an oven at a set temperature of 105 0C for 3 hours. The sample shall be brought out after every 3 hours and re – weighed until a constant weight shall be obtained. The  weight shall be recorded as W3. Moisture content shall be evaluated using equation 1.  

% Moisture Content =   W2 – W3    x 100 ……………………. (1)
                                          W2 – W1         1  
Where:                                                                                                                                  
W1   =   weight of empty petri dish.
W2   =   weight of petri dish and sample before drying.
W3   =    weight of petri dish and sample after drying
3.4       Physical Properties
3.4.1   Size Characteristics
The physical dimension of the paddy rice and milled rice shall be determined by measuring the length, width and thickness of 100 kernels using a vernier caliper having 0.01mm accuracy as shown in Figure 3.1. The longest dimension of the seed will be clipped with a vernier caliper and the reading of the main scale and vernier scale shall be taken. The two readings shall be added together to obtain the length value of the seed.
The side of the seeds shall be clipped with a vernier caliper and the reading shall be taken to obtain the width of the rice seed.
The vernier shall be used to clip the dimension that opposes the length and the width of the seeds. The main and vernier scales shall be summed up to get the thickness of the rice seeds.

 
Figure 3.1: Vernier Caliper
Source:    Okeke and Anyakoha (2000)

3.4.2 Geometric Mean Dimension (De)
            The geometric mean dimension (De) of the rice kernel shall be found using the relationship (equation 2) given by Mohsenin (1986) as:
De        =             (LWT) 1/3          ---------------------------------- (2)                          
Where:                      
L          =         Length of seed (mm)                                                                                   
W        =          Width of seed (mm)                                                                        
T          =          Thickness of seed (mm)     
3.4.3    Sphericity and Aspect Ratio
            The criteria used to describe the shape of the seed are the sphericity and aspect ratio. Thus, the sphericity (Ø) shall be computed using the equation given by Mohsenin (1986) as:
   Ø      =          (LWT)1/3 x 100         ---------------------------------- (3)
                              L                1
Where:
L          =         Length (mm)
W         =          Width (mm)
T          =          Thickness (mm)
The aspect ratio (Ra) will be calculated using equation 4 according to Maduako and Faborode (1990) as:
            Ra    =       W/L x    100 -------------------------------------------- (4)
Where:
L          =         Length (mm)
W         =         Width (mm)
3.4.4   Thousand Grain Weight
            This shall be carried out by counting 100 kernels and weighing them in an electronic balance and then multiplying by 10 to give the mass of 1000 grains (Gayin, et al., 2009).
3.4.5   Surface Area (sa)
            The surface area shall be calculated using the relationship (equation 5) by McCabe et al. (2005) as:
  Sa = pieD2e -----------   (5)

Where:
 Pie = 22/7
 De = Geometric mean dimension (mm)
Sa = surface Area (mm2)                                                                                                
3.4.6 Determination of Bulk Density                                                                 
          The bulk density shall be determined using a pycnometer bottle. This shall be done by filling a container with a known volume of water from a height of 150 mm at a constant rate and then, the content shall be weighed. No separate compaction of seeds shall be done. The bulk density shall be calculated using equation 6 (Abalone et al., 2004, Kinsley et al., 2006).                                     
            Bulk Density = M/L-------------------------------------- (6)                     
Where:
M        =          mass of the seeds (g)                                                                                                  V      =            volume of container (ml)
3.4.6.1            True Density
The True Density (ρt) is defined as the ratio of mass of seed to the solid volume occupied (Deshpande et al., 1993). The seed volume shall be determined using liquid displacement technique. Toluene shall be used in spite of water so as to prevent the absorption during measurement and also to get the benefit of low surface tension of selected solvent (Sitkei, 1986, Ogut, 1998, Singh and Goswami, 1996). True density (ρt) shall be evaluated using equation 7 (Mohsenin, 1986).
V =      Mtd     =   (Mt – Mp) – (Mpts – Mps) ----------------7
              Pt                                           Pt
ρs =         Mps  - Mp ------------------------------------------    8
                   V
Where:
            V         =          seed volume (cm3)
                Mtd        =          mass of displaced toluene (g)
             ρt        =          toluene density  (g/cm3)
                Mt          =          mass of pycnometer and toluene (g)
            Mp         =          mass of empty pycnometer (g)
            Mpts      =          mass of pycnometer filled with toluene and sample (g)
            Mps       =          mass of pycnometer and seeds (g)
            ρs           =          seed density (g/cm3)

3.4.7               Porosity 
            The porosity (ε) of bulk seed shall be computed from the values of the true density (ρt) and bulk density (ρb) using the relationship (equation 9) given by Mohsenin (1986) as.
ε = 1- pb        x 100 ---------------------------------------- (9)
pt        
Where: 
ε          =          porosity (%)                                                                                                  Pt         =            True density (g/ml)                                                                                      Pb        =          bulk density (g/ml)
3.4.8   Angle of Repose
            The angle of repose (θ) considered as the angle in degrees with the horizontal at which the material will stand forming a heap shall be determined by using an apparatus in (Figure 3.2) consisting of a plywood Box (140*160*35mm) and two plates: fixed and adjustable .The box shall be filled with the sample and placed on a surface, and then lifting up the box gradually, allowing the sample to accumulate and form a conical heap on the surface. Then, the angle of repose shall be calculated from the ratio of the height to the base radius of the heap formed (Mohsenin 1986; Serpil and Servant 2006; Kaleemullah, 1992). 
Where:
θf = Angle of repose (deg.)
H = Height (mm)
D = Diameter of the cone (mm).

3.4.9   Static Coefficient of Friction (μ)
            The static coefficient of friction (μ) shall be determined for three structural materials namely glass, plywood, and galvanized steel sheet. A plastic cylinder of 50 mm diameter and 60 mm height shall be placed on an adjustable tilting flat plate faced with the test surface and filled with the sample of about l00g. The cylinder shall be raised slightly so that it does not touch the surface. The structural surface with the cylinder resting on it shall be inclined to slide down. This is shown in Figure 3.3.
            The angle of tilt shall be noted and tangent of the angle shall be reported as coefficient of static friction (Dutta et al., 1988; Fraser et al., 1978; Shepherd and Bhardwaj, 1986).                                                                                                     

3.10    STATISTICAL ANALYSIS
            All the data generated shall be subjected to a One-Way Analysis of Variance (ANOVA) in CRD, and the Duncan’s Multiple Range test shall be used  to separate the  mean using SPSS software package (Version, 17.0) significance shall be accepted at p <0.05.
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